A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap.

نویسندگان

  • Yang Chen
  • Jesse D Sokolow
  • Elzbieta Trzop
  • Philip Coppens
چکیده

A three-dimensional coordination polymer based on a manganese-doped polyoxotitanate nanocluster, {Ti13Mn4O16[MeC(CH2O)3]4(OEt)12Br4}∞, has been synthesized under solvothermal conditions. It is the first framework of doped polyoxotitanate nanoclusters reported in the literature. Compared with anatase, its band gap is reduced from 3.19 to 2.57 eV.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 43  شماره 

صفحات  -

تاریخ انتشار 2013